Wednesday, May 11, 2016

Ideal Gas Law

Note: Pressure must be in atm, volume must be in L, and 
temperature must be in K. The constant R is .0821 L atm/ mol K. 

Modeled on the Kinetic Theory of Gases which has 4 basic postulates:
  • Gases consist of molecules which are in continuous random motion
  • The volume of the molecules present is negligible compared to the total volume occupied by the gas
  • Intermolecular forces are neglibible
  • Pressure is due to the gas molecules colliding with the walls of the container
Example: Calculate the volume (L) occupied by 7.40 g NH3 at STP. 

First, list the knowns. 
  • V= ?
  • T=273.15K
  • P= 1.00 atm
  • n= 7.40 g x (1 mol/17.04g) = .434 g
  • R=.0821
Then, plug in the values into the equation to solve for V. 
  • PV=nRT
  • 1.00V=.434 x .0821 x 273.15
  • V = 9.73 L 

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